Otimização do processo foto-fenton com irradiação UV no tratamento de efluentes de indústria de processamento de subprodutos de alimentos

Fernando Rodolfo Espinoza-Quiñones; Diego Ricieri Manenti; Fernando Henrique Borba; Soraya Moreno Palácio; Aparecido Nivaldo Módenes; Katiussia Stela Crestani; Paulo Roberto Schmidt Junior; Rogério do Nascimento

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Otimização do processo foto-fenton com irradiação UV no tratamento de efluentes de indústria de processamento de subprodutos de alimentos

Fernando Rodolfo Espinoza-Quiñones, Diego Ricieri Manenti, Fernando Henrique Borba, Soraya Moreno Palácio, Aparecido Nivaldo Módenes, Katiussia Stela Crestani, Paulo Roberto Schmidt Junior, Rogério do Nascimento

Resumo

Neste trabalho, foi investigada a remoção de poluentes orgânicos do efluente de uma indústria de transformação alimentícia com base na técnica foto-Fenton, utilizando irradiação artificial, em escala laboratorial. Como fontes de irradiação UV, foram fixadas três lâmpadas comerciais de mercúrio acima do reator foto-Fenton dentro de uma caixa isolada. Foi aplicado um planejamento fatorial 2³ a fim de otimizar o processo foto-Fenton baseado na avaliação dos valores da demanda química de oxigênio (DQO), da cor e da turbidez. O modelo estatístico de segunda ordem proposto resultou em um bom ajuste linear, com as variáveis pH inicial e as concentrações de Fe²⁺ e H₂O₂ sendo estatisticamente significativas para a remoção da DQO e da cor. O melhor desempenho do processo foto-Fenton artificial foi alcançado para as concentrações de Fe²⁺ = 0,26 g L^-1 e H₂O₂ = 22,0 g L^-1, e o pH inicial em 3,0. Nestas condições, o processo obteve ótima eficiência na remoção dos parâmetros com apenas 10 minutos de reação, apresentando 93% na redução da DQO, 95% de descoloração e 98% de redução da turbidez.

Palavras-chave

poluentes orgânicos; processo oxidativo avançado; planejamento experimental

Texto completo:

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Revista Ciências Exatas e Naturais - RECEN. Universidade Estadual do Centro-Oeste - UNICENTRO/PR, BRASIL.

Licenciada sob uma Licença Creative Common

ISSN 2175-5620 ON LINE; 1518-0352 IMPRESSO

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Otimização do processo foto-fenton com irradiação UV no tratamento de efluentes de indústria de processamento de subprodutos de alimentos

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